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Influences of Chemical Functionalities on Crystal Structures and Electrochemical Properties of Dihydro-benzoxazine Dimer Derivatives

2021

Dihydro-1,3,2H-benzoxazine dimer derivatives or dihydro-benzoxazine dimers are a class of compounds typically prepared by ring-opening reactions between dihydro-benzoxazines and phenols. Dihydro-benzoxazine dimers act as chelating agents for several transition and rare-earth cations. To better understand the chelating properties, it is necessary to examine their structural features and electrochemical characteristics thoroughly. However, the electrochemical properties of dihydro-benzoxazine dimers have not been tremendously examined. Herein, eight derivatives of dihydro-benzoxazine dimers possessing different substituents on the benzene ring and the tertiary-amine nitrogen were synthesized …

crystal structureCrystallographyHydrogen bondGeneral Chemical EngineeringDimerHirshfeld surfaceIntermolecular forceCrystal structureCondensed Matter PhysicsRedoxInorganic ChemistryCrystalelectrochemical propertychemistry.chemical_compoundCrystallographychemistryQD901-999General Materials SciencebenzoxazineCyclic voltammetryMethyleneCrystals
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